The student Patricia Vasconcellos de Almeida, 22, tried to kiss one of the military police who formed a cordon ostensibly in front of the building Fetranspor (Federation of Transport Companies), in Rio de Janeiro, on June 27, 2013. (Photo by Zulmair Rocha/UOL)

Photographer Howard Schatz had an idea: place actors in a series of roles and dramatic situations to reveal the essence of their characters. Such was the premise behind his book, In Character: Actors Acting, which captures some of Hollywood’s most emotive stars in the act of, well, making faces. Luckily for us, he continued the tradition for Vanity Fair. Here are some of the best.

A biker shows his 12-year-old cat “Chiquinho” – which always rides with him on his motorbike – in Rio de Janeiro, Brazil, on June 19, 2016. (Photo by Yasuyoshi Chiba/AFP Photo)

2016 Rio Olympics, Beach Volleyball, Women's Preliminary, Beach Volleyball Arena, Rio de Janeiro, Brazil on August 6, 2016. Liliana Fernandez Steiner (ESP) of Spain prepares to serve. (Photo by Ruben Sprich/Reuters)

Praia du Forte, Bahia. “This was the lead picture for a National Geographic story on Bahia, because it was both mysterious as well as a “geography” picture showing where the slaves arrived from Nigeria. Beach pictures seem like they should be easy to take, but for me they are actually quite difficult. Too easy to fall into cliche. When I saw the kid coming on the horse, I quickly ran to see if I could make something with a woman in a bikini that was not a bikini shot”. (Photo by David Alan Harvey/The Guardian)

An Iraqi soldier stands guard as a pipeline burns in the background after an explosion 30 kilometers (20 miles) northeast of Tikrit, Iraq, Monday, February 11, 2008. (Photo by Bassem Daham/AP Photo)

This photo provided by Steamboat Ski Resort shows hot air balloons that visitors can tour in above the town and mountains in Steamboat Springs, Colo. Wild West Adventures offer continental breakfast, champagne ceremony with flight certificates and courtesy pick-up are included. (Photo by Larry Pierce/AP Photo/Steamboat Ski Resort)

“YagYang”. The Apatani are tribal people living in north east of India in the region of Arunachal Pradesh. Tattooing and stuffing of large nose plugs is the particularity of these women. YagYang 75 years old, her husband passed away few months ago and she feels very alone, during my visit I was very fond of this woman and I wanted to spend some more time with her, so I asked her which was her favorite dish. The next day i returned with the fresh fish, as she mentioned, and when she saw me she was very happy and welcomed me with a big smile. Photo location: India. (Photo and caption by Passarini Mattia/National Geographic Photo Contest)